PetroChina Company Limited
Spherical supported transition metal catalyst

Abstract:

The present invention provides a spherical supported transition metal catalyst. The catalyst carrier is a spherical titanium/zirconium hydrophosphate compound, the primary catalyst is a transition metal compound, the co-catalyst is methylaluminoxane; the spherical titanium/zirconium hydrophosphate compound comprises one or several combinations of titanium hydrophosphate, modified titanium hydrophosphate and zirconium hydrophosphate. The present invention also provides a preparation method of said spherical supported transition metal catalyst and a use thereof in olefin polymerization, as well as the spherical titanium/zirconium hydrophosphate compound and its preparation method. The spherical, supported transition metal catalyst in the present invention has a high catalytic activity, and the polymer particles obtained have good morphology.